Size distribution of sulfur species in fine and ultrafine aerosol particles using sulfur K-edge XANES

LIN Jun; BAO Liang-Man; LIU Wei; LI Yan; LI Yu-Lan; MA Chen-Yan; ZHAO Yi-Dong

doi:10.1088/1674-1137/33/11/007

Chinese Physics C> 2009, Vol. 33> Issue(11) : 965-968 DOI: 10.1088/1674-1137/33/11/007

Size distribution of sulfur species in fine and ultrafine aerosol particles using sulfur K-edge XANES

Abstract
HTML
Reference
Related

PDF

Abstract：
The sulfur species existing in different size aerosol particles were determined based on the `white line' energy shift and the features of post edge structure of sulfur K-edge XANES (X-ray Absorption Near Edge Structure). The results indicated that sulfates were dominant sulfur species in aerosol particles. However, small amount of reductive sulfur species were also found in the ultrafine aerosol particles(<0.1 μm). Sulfates in aerosols mostly exhibited as (NH₄)₂SO₄ and gypsum. Most (NH₄)₂SO₄ distributed in aerosol particles finer than 0.952 μm, while gypsum was the dominant sulfate in coarse aerosols.

References

[1]

. Kiehl J T, Briegleb B P. Science, 1993, 260(5106): 311-3142. Haywood J M, Roberts D L, Slingo A et al. Journal of Climate, 1997, 10(7): 1562-15773. Sullivan T J, Cosby B J, Tonnessen K A et al. Water Resources Research, 2005, 41(1): W010214. Doney S C, Mahowald N, Lima I et al. Proceedings of the National Academy of Sciences, 2007, 104(37): 145805. Arimoto R. Chinese Journal of Geochemistry, 2006, 25:220-2206. LIU J, Mauzerall D. Geophysical Research Abstracts, 2007,9: 51117. Oberdorster G, Oberdorster E, Oberdorster J. Environmental Health Perspectives, 2005, 113(7): 823-8398. Prange A, Modrow H. Reviews in Environmental Scienceand Biotechnology, 2002, 1(4): 259-2769. Fleet M E. Canadian Mineralogist, 2005, 43(6): 181110. Takahashi Y, Kanai Y, Kamioka H et al. Environ Sci Technol,2006, 40(16): 5052-711. Matsumoto S, Tanaka Y, Ishii H et al. Spectrochimica ActaPart B: Atomic Spectroscopy, 2006, 61(8): 991-99412. Pingitore N E, Meitzner G, Love K M. Geochimica et Cosmochimica Acta, 1995, 59(12): 2477-248313. Solomon E I, Hedman B, Hodgson K O et al. Coordination Chemistry Reviews, 2005, 249(1-2): 97-12914. YI R Q, YANG G H, CUI Y L et al. Acta Physica Sinica,2006, 55(12): 6287-6292 (in Chinese)15. ZHENG L, ZHAO Y D, CUI MQ et al. Nuclear Techniques,2007, 30(9): 721-724 (in Chinese)16. Suguira C. Journal of Chemistry and Physics, 1981, 74(1):215-21717. Waldo G S, Carlson R M K, Moldowan J M et al. Geochimicaet Cosmochimica Acta, 1991, 55(3): 801-81418. Rompel A, Cinco R M, Latimer M J et al. Proceedings ofthe National Academy of Sciences of the United States ofAmerica, 1998, 95(11): 612219. XIA K, Weesner F, Bleam W F et al. Soil Science, 1998,62(5): 1240-124620. Vairavamurthy A. Spectrochimica Acta Part A: Molecularand Biomolecular Spectroscopy, 1998, 54(12): 2009-201721. Prange A, Arzberger I, Engemann C et al. Biochemica etBiophysica Acta, 1999, 1428(2-3): 446-45422. Prietzel J, Thieme J, Neuhausler U, Susini J et al. European Jounal of Soil Science, 2003, 54: 423-43323. Prietzel J, Thieme J, Salomé M et al. Soil Biology and Biochemistry,2007, 39(4): 877-89024. Sarret G, Connan J, Kasrai M et al. Geochimica et Cosmochimica Acta, 1999, 63(22): 3767-377925. Morra M J, Fendorf S E, Brown P D. Geochimica et Cosmochimica Acta, 1997, 61(3): 683-68826. Hien P D, Bac V T, Thinh N T H. Atmospheric Environment,2005, 39(38): 7231-723927. WANG Y, ZHUANG G, TANG A et al. Atmospheric Environment,2005, 39(21): 3771-378428. Spurny K R. Aerosol Chemical Processes in the Environment.Lewis Publishers Boca Raton, Fla, 200029. Mori I, Nishikawa M, Iwasaka Y. Science of the Total Environment,1998, 224(1-3): 87-91

[1]	LIU Li-Juan , LIU Hui-Jun , CUI Ming-Qi , HU Yong-Feng , ZHENG Lei , ZHAO Yi-Dong , MA Chen-Yan , XI Shi-Bo , YANG Dong-Liang , GUO Zhi-Ying , WANG Jie . Determination of the calcium species in coal chars by Ca K-edge XANES analysis. Chinese Physics C, 2013, 37(2): 028003. doi: 10.1088/1674-1137/37/2/028003
[2]	JIA Quan-Jie , CHEN Yu , LI Gang , JIANG Xiao-Ming . Optimization of the in-line X-ray phase-contrast imaging setup considering edge-contrast enhancement and spatial resolution. Chinese Physics C, 2012, 36(3): 267-274. doi: 10.1088/1674-1137/36/3/014
[3]	WANG Yang-Yang , ZHAO Lin-Jie , YUAN Zhong-Sheng , ZHANG Dan-Dan , FANG Wei , XU Ming-Mei . System size in relativistic heavy ion collisions. Chinese Physics C, 2011, 35(3): 264-268. doi: 10.1088/1674-1137/35/3/010
[4]	FU Zi-Wen , Carleton DeTar . Scalar meson spectroscopy with a fine lattice. Chinese Physics C, 2011, 35(10): 896-901. doi: 10.1088/1674-1137/35/10/002
[5]	WU Feng , YE Wei . System size effects on probing nuclear dissipation with neutrons. Chinese Physics C, 2010, 34(5): 551-554. doi: 10.1088/1674-1137/34/5/007
[6]	SHEN Cheng-Ping (for the Belle collaboration) . XYZ particles at Belle. Chinese Physics C, 2010, 34(6): 615-620. doi: 10.1088/1674-1137/34/6/001
[7]	ZHAO Ting , GAO Bin , LIU Lei , YE Qing , CHU Wang-Sheng , WU Zi-Yu . Theoretical XANES spectra for C₇₆ isomers. Chinese Physics C, 2009, 33(11): 954-959. doi: 10.1088/1674-1137/33/11/005
[8]	BAO Liang-Man , ZHANG Gui-Lin , ZHANG Yuan-Xun , LI Yan , LIN Jun , LIU Wei , CAO Qing-Chen , ZHAO Yi-Dong , MA Chen-Yan , HAN Yong . Transfer characterization of sulfur from coal-burning emission to plant leaves by PIXE and XANES. Chinese Physics C, 2009, 33(11): 1010-1015. doi: 10.1088/1674-1137/33/11/016
[9]	BAO Liang-Man , LIN Jun , LIU Wei , LU Wen-Zhong , ZHANG Gui-Lin , LI Yan , MA Chen-Yan , ZHAO Yi-Dong , HE Wei , HU Tian-Dou . Investigation of sulfur speciation in particles from small coal-burning boiler by XANES spectroscopy. Chinese Physics C, 2009, 33(11): 1001-1005. doi: 10.1088/1674-1137/33/11/014
[10]	SUN Zhu , LIU Fu-Hu . Multiplicity distribution of final-state particles and different contributions of related sources in nucleus-nucleus collisions at high energies. Chinese Physics C, 2008, 32(9): 740-743. doi: 10.1088/1674-1137/32/9/011
[11]	ZHU Jian-Yu , XU Fu-Rong . Spin-orbit potential in sulfur isotopes. Chinese Physics C, 2008, 32(S2): 155-157.
[12]	GUO Xiao-Yun , CHU Wang-Sheng , GONG Wei-Min , DONG Yu-Hui , XIE Ya-Ning , YANG Fei-Fei , Maurizio Benfatto , WU Zi-Yu . MXAN Analysis of the XANES Energy Region of LiPDF. Chinese Physics C, 2007, 31(2): 199-203.
[13]	HU Rong , WU Zi-Yu , LIU Jing , XIE Ya-Ning , HU Tian-Dou , ZHANG Jing , FENG Wei-Yue , CHAI Zhi-Fang . XANES Investigation of Chromium Valence State in Yeast Biomass. Chinese Physics C, 2004, 28(1): 100-103.
[14]	CHU Wang-Sheng , HU Tian-Dou , XIE Ya-Ning , LIU Wen-Han , WU Zi-Yu , . Metal K-edge XAS Study of AlB2-type Transition-metal Diborides. Chinese Physics C, 2003, 27(S1): 10-14.
[15]	JI Yun-Liang , HU Rong , WU Zi-Yu , GUO Lin , XU Hui-Bin , ZHANG Jing , XIE Ya-Ning , HU Tian-Dou . XANES Investigation of Synthesized Nano-ZnO Capped by DDAB. Chinese Physics C, 2003, 27(4): 367-370.
[16]	Ye Wei , Shen Wenqing , Ma Yugang , Feng Jun , K. Yoshida , T. Nakagawa , K. Yuasa-Nakagawa , K. Furutaka , K. Matsuda , Y. Futami , S. M. Lee , J. Kasagi . Azimuthal Distribution and Azimuthal Correlation of Light Particles Emitted in 10.6MeV/u ⁸⁴Kr + ²⁷Al Collision. Chinese Physics C, 1997, 21(S1): 417-424.
[17]	Huo Lei , Liu Yiming , Zhang Weining , Jiang Yuzhen , D. Keane , S. Y. Fung . Polar Distribution of Final State Particles in High-Energy Heavy Ion Collisions. Chinese Physics C, 1996, 20(S2): 141-147.
[18]	Liu Bo , Zhao Weiqin . Rapidity Distribution of Negatively Charged Particles in RHIC. Chinese Physics C, 1991, 15(S2): 159-163.
[19]	Zheng Bo . A (l+l)-Dimensional Lattice U(l) Gauge Model and the Fermion Species Doubling. Chinese Physics C, 1990, 14(S3): 249-254.
[20]	Wang Shaoshun , Zhang Jie , Xiao Chenguo , Ye Yunxiu , Shi Guoshun , Fang Rong , Yang Jie . Multiplicity Distribution of Charged Particles Produced in pp Collisions at 400 GeY/c. Chinese Physics C, 1989, 13(S3): 231-238.

Access

Get Citation

LIN Jun, BAO Liang-Man, LIU Wei, LI Yan, LI Yu-Lan, MA Chen-Yan and ZHAO Yi-Dong. Size distribution of sulfur species in fine and ultrafine aerosol particles using sulfur K-edge XANES[J]. Chinese Physics C, 2009, 33(11): 965-968. doi: 10.1088/1674-1137/33/11/007

RIS(for EndNote,Reference Manager,ProCite)

BibTex

Txt

Milestone

Received: 2008-12-17
Revised: 2009-04-01

Article Metric

Article Views(2786)
PDF Downloads(694)
Cited by(0)

Policy on re-use

To reuse of subscription content published by CPC, the users need to request permission from CPC, unless the content was published under an Open Access license which automatically permits that type of reuse.

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Size distribution of sulfur species in fine and ultrafine aerosol particles using sulfur K-edge XANES

Corresponding author: LIN Jun,

Received Date: 2008-12-17

Accepted Date: 2009-04-01

Available Online: 2009-11-05

Abstract:

The sulfur species existing in different size aerosol particles were determined based on the `white line' energy shift and the features of post edge structure of sulfur K-edge XANES (X-ray Absorption Near Edge Structure). The results indicated that sulfates were dominant sulfur species in aerosol particles. However, small amount of reductive sulfur species were also found in the ultrafine aerosol particles(<0.1 μm). Sulfates in aerosols mostly exhibited as (NH₄)₂SO₄ and gypsum. Most (NH₄)₂SO₄ distributed in aerosol particles finer than 0.952 μm, while gypsum was the dominant sulfate in coarse aerosols.

HTML

Reference (1)

Size distribution of sulfur species in fine and ultrafine aerosol particles using sulfur K-edge XANES

Abstract：

References

Access

Article Metrics

Metrics

通讯作者: 陈斌, bchen63@163.com

Email This Article