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《中国物理C》(英文)编辑部
2024年10月30日

The Morphology of CDA-g-PMMA Copolymers in Solution Studied by SR-SAXS

  • The morphology of a series of well-defined graft copolymers of diacetate cellulose and PMMA was studied through SR-SAXS. The graft copolymer formed mono-molecular sphere in the solution of CCl2H2 and CH3OH. And the dimension of the graft copolymer increased with the increasing of the degree of polymerization of the PMMA side chains.
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  • [1] . GAO Jie. Progress in Cellulose Graft Copolymerization,Chinese Science Bulletin, 1964, 12: 1092—1099(in Chinese)(高洁.纤维素接枝共聚合的进展,科学通报,1964, 12: 1092-1099)2. Stannett V. Some Challenges in Grafting to Cellulose andCellulose Derivative, ACS Symp. Ser., 1982, 187: 3—203. Battacharyya S N, Maldas D. Graft Copolymerization OntoCellulosics, Prog. Polym. Sci., 1984, 10: 171—2704. Hebeish A, Guthrie J T. The Chemistry and Technologyof Cellulosic Copolymers, Berlin Heideberg, New York:Springer-Verlog, 19815. Alekseeva O V et al. Russ. J. Phys. Chem., 2000, 74:1276—12786. Roder T et al. Polymer, 2001, 42: 6765—67737. CAI Tong, HU Zhi-Bing, Langmuir, 2004, 27: 7355—73598. DOU Hong-Jing et al. Angew. Chem., 2003, 115: 1554—15579. YUE Z, Cowie J M G. Polymer, 2002, 43: 4453—446010. YUE Zhi-Lian, John M G. Cowie, Macromolecules, 2002,35: 6572—657711. Mark H. Physik und Chemie der Zellulose, Springer, 1932,13912. Warren B E. J. Chem. Phys., 1934, 2: 551—61913. Glatter O, Kraty O. Small Angle X-Ray Scattering, NewYork, Academic Press, 198214. Guinier A, Fournet G. Small Angle Scattering of X-Rays,New York and London, John Wiley Sons and Chapmanand Hall, 195515. Debye A, Bueche A M. J. Appl. Phys., 1949, 20: 518—52616. HU Jia-Cong. X-Ray Diffraction by Macromolecules, 1stEdition, Beijing: Science Press, 2003. 452—501(in Chinese)(胡家璁.高分子X射线学,第一版,北京:科学出版社,2003.452-501)17. MENG Zhao-Fu. Theory and Application of Small AngleX-ray Scattering, 1st Edition, Changchun: Julin Scienceand Technology Press, 1995(in Chinese)(孟昭富.小角X射线散射理论及应用,第一版,长春:吉林科学技术出版社,1995)
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SHEN Da-Wa, YU Hui, WU Zong-Hua and HUANG Yong. The Morphology of CDA-g-PMMA Copolymers in Solution Studied by SR-SAXS[J]. Chinese Physics C, 2005, 29(S1): 8-11.
SHEN Da-Wa, YU Hui, WU Zong-Hua and HUANG Yong. The Morphology of CDA-g-PMMA Copolymers in Solution Studied by SR-SAXS[J]. Chinese Physics C, 2005, 29(S1): 8-11. shu
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Received: 2005-10-28
Revised: 1900-01-01
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The Morphology of CDA-g-PMMA Copolymers in Solution Studied by SR-SAXS

    Corresponding author: WU Zong-Hua,
  • State Key Laboratory of Polymer Chemistry and Physics, Institute of Chemistry,Chinese Academy of Sciences, Beijing 100080, China2 Beijing Synchrotron Radiation Facility, Institute of High Energy Physics,Chinese Academy of Sciences, Beijing 100049, China

Abstract: The morphology of a series of well-defined graft copolymers of diacetate cellulose and PMMA was studied through SR-SAXS. The graft copolymer formed mono-molecular sphere in the solution of CCl2H2 and CH3OH. And the dimension of the graft copolymer increased with the increasing of the degree of polymerization of the PMMA side chains.

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